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Mechanistic investigations demonstrated that when the 1,2-dithiolane moiety was conjugated via carbamate linkages to targeted molecular architectures for the development of stimuli-responsive prodrugs or probes, GSH-mediated only partial reduction of the intracyclic disulfide bonds, whereas TrxR consistently exhibited markedly higher catalytic efficiency in the cleavage process 23,24

Consequently, therapies that reduce systemic inflammation could theoretically influence iron availability

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