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The photochemical production of singlet oxygen is mainly due to quenching of the excited triplet state of suitable sensitizers: Singlet oxygen exhibits several specific reactions and the one that has been most often invoked in the photooxidation of polymers is the formation of a hydroperoxide by oxidation of an olefin containing an allylic hydrogen, and which could further decompose and lead to chain scission and formation of a terminal of carbonyl group

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