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In the brain this is most likely catalyzed by pyruvate carboxylase (PC) which has a higher activity than the other enzymes capable of synthesizing oxaloacetate, i.e., malic enzyme (ME) and phosphoenolpyruvate carboxykinase ( de novo synthesis of the carbon skeleton of glutamate and GABA via glutamine requires astrocytic participation [see Ref

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5 Ultraviolet radiation can cause immunosuppression by: disturbing the way antigens are processed by the immune system, stimulating cytokines that can suppress the immune system and by altering contact and delayed hypersensitivity reactions

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Garber, A., et al